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The release of highly toxic tellurite into the aquatic environment poses significant environmental risks. The acceleration mechanism and tellurium nanorods (TeNPs) characteristics with bioavailable ferric citrate (Fe(III)) were investigated in the tellurite (Te(IV)) bioreduction. Experiments showed that 5 mM Fe(III) increased the Te(IV) bioreduction rate from 0 to 12.40 mg/(L·h). Cyclic voltammetry, electrochemical impedance spectroscopy and Tafel were used to investigate electron transfer during Te(IV) bioreduction. NADH production (elec
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