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3 ps) and charge recombination (CR, 238 ps) processes outcompete the torsion-induced nonradiative decay and induce fast ISC through the SOCT-ISC mechanism. The triplet quantum yield of the electron donor/acceptor dyad is highly dependent on solvent polarity (ΦT = 1.9-45%), which supports the SOCT-ISC mechanism, and the triplet-state lifetime is up to 247.3 μs. Using the electron donor-acceptor dyad showing SOCT-ISC as a triplet photosensitizer, efficient triplet-triplet annihilation (TTA) upconversion was observed with a quantum yield

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