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The best results were obtained based on the first derivative of absorption signal. The correct identification rate of the Ag forms was only in the range 25-60% depending on the composition of the tested samples, that indicates limitations of this approach. For estimating the concentrations of the Ag forms, partial least squares regression (PLSR) was implemented. The errors levels (expressed as the root mean squared error of prediction of concentration) for mixtures were acceptable and comparable between the studied databases. The develo
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