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Previously, we have reported the successful preparation of micrometer-sized poly(methyl methacrylate) particles without submicrometer-sized byproduct particles by microsuspension iodine-transfer polymerization (ms ITP), in which the radical exit depression (RED) effect was expected, with the benzoyl peroxide initiator at 8 wt % relative to the monomer. However, it was difficult to apply it simply under a similar condition for methyl acrylate (MA), which is more hydrophilic than methyl methacrylate (MMA), because the polymerization rate i
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