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First, a monolayer was created by immersion in a NH2-Ar-SO3H answer, permitting aryldiazonium salt radicals to spontaneously bind to it via powerful C bonding. After formation associated with the air-stable and thick molecular monolayer (-Ar-SO3H), a subsequent activation was utilized to form very reactive -Ar-SO2Cl groups almost perpendicular to the monolayer. These can bind commercial surfactants, PEGylated oligomers also inexpensive molecules via their -OH, -COOH, or -N