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Global need for transformation from fossil-based to bio-based economy is constantly emerging for the production of low-carbon/renewable energy/products. Microbial fuel cell (MFC) catalysed by bio-electrochemical process gained significant attention initially for its unique potential to generate energy. Diversification of MFC is an emerging trend in the context of prioritising/enhancing product output while exploring the mechanism specificity of individual processes. Bioelectrochemical treatment system (BET), microbial electrosynthesis