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6 at 923 K). Our research results provide a strong theoretical basis for the experimental exploration of the TE properties of RbAgM, and help to promote further experimental verification.Herein, a simple and practical method for generating isoacenofuran, a new π-extended quinoidal building block, was developed. A three-step protocol involving double nucleophilic additions of alkynyllithiums to acene-2,3-dicarbaldehyde, mono-oxidation, and acid-promoted cyclization enables the generation of the target molecule, which is trapped by a dienophile to produce hig
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