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Furthermore, to shed light on the dynamical heterogeneity, ion pair, ion cage, and hydrogen-bond stabilities and also the reorientation dynamics of ions have been investigated. Results demonstrated that local dynamics differences originate from local structural heterogeneity.We herein described a selenylative cyclization reaction of enynes by the utilization of diselenides as radical sources. The visible-light irradiation of the reaction mixture enables the generation of the selenium atom radical to trigger the radical addition/cycliza