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When coupled with O2-reducing biocathode, MnOx/Ti anode considerably accelerated M(·OH) generation because Ea increased. The increased Ea in BECR was due to the fact that its cathodic reaction was converted to the four-electron O2 reduction, which exhibited a higher cathodic potential than hydrogen evolution reaction on SS cathode in ECR-SS. Thereby, BECR simultaneously promoted dye removal and reduced energy consumption, showing promise in treating dyeing wastewater. Black carbon (BC) exerts important radiative effects over regions with