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Consequently, the focal adhesion areas were significantly decreased, resulting in impaired cell adhesion. © 2020 Wiley Periodicals, Inc.Chiral acyclic tertiary allylic alcohols are very important synthetic building blocks, but their enantioselective synthesis is often challenging. A major limitation in catalytic asymmetric 1,2-addition approaches to ketones is the enantioface differentiation by steric distinction of both ketone residues. In this communication we report the development of a catalytic asymmetric Meisenheimer rearrangement

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