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The formed BAIL-water nano-interfaces in reverse μEs have exerted a positive effect on the catalytic activity of Cyt-c stored in a water pool of reverse μEs. A five-fold higher rate constant in μEs as compared to buffer establishes μEs as a better catalytic medium. Furthermore, the differing nature of nano-interfaces created by BAILs and water in reverse μEs, depending on the functionalization of the alkyl chain of the cationic part of BAIL, has exerted varying influence on the catalytic activity of Cyt-c. It is expected that the prese