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Therefore, RL provides a good framework to tailored design approaches for different discovery phases.Reaction of [Ru(PPh3)3HCl] with LiCH2TMS, MgMe2, and ZnMe2 proceeds with chloride abstraction and alkane elimination to form the bis-cyclometalated derivatives [Ru(PPh3)(C6H4PPh2)2H][M'] where [M'] = [Li(THF)2]+ (1), [MgMe(THF)2]+ (3), and [ZnMe]+ (4), respectively. In the presence of 12-crown-4, the reaction with LiCH2TMS yields [Ru(PPh3)(C6H4PPh2)2H][Li(12-crown-4)2] (2). These four complexes demonstrate increasing interaction between
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