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This manuscript reports four new gold(I)-silver(I) complexes with 2-(2-pyridyl)-1,8-naphthyridine (pyNP) and terpyridine (terpy) as ancillary ligands, having formulae [Ag(pyNP)(Au(CN)2)]2 (1), [Ag2Au2(μ-CN)2(CN)2(pyNP)2] (2), [Ag2Au(μ-CN)2(terpy)2][Au(CN)2] (3) and [Ag4Au4(μ-CN)8(terpy)2(py)] (4). Complexes 1 and 2 are structural isomers obtained from different solvents. The Au(CN)2- anion is not coordinated and establishes intramolecular Au⋯Ag,Ag interactions in 1. In contrast, it is monocoordinated to silver atoms via a CN fragment i
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