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Applying Debye-Slater and the Debye - Grüneisen models the thermal expansion coefficient, heat capacity and entropy are found and their temperature dependence is discussed. © 2020 IOP Publishing Ltd.Heterostructures composed of nano-/micro-junctions, combining the excellent photon harvesting properties of nano-system and ultrafast carrier transfer of micro-system, have shown promising role in high-performance photodetectors. Here, in this paper a highly-sensitive trilayer self-powered perovskite-based photodetector ITO/ZnO(70nm)/CdS(150nm