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Interesting oligomerization of this uranyl groups from three kinds of tetrameric products in 1 and 2 to octameric [(UO2)8(μ3-OH)6(μ2-OH)2(H2O)4]8+ in 3 and eventually unlimited polyoxouranium stores in 4 had been observed. The 3D structure of 2 contains two different linear tetramers, whose frameworks tend to be completely different from seven kinds of tetranuclear motifs previously noticed in uranyl carboxylates. Mixture 3 displays a rare octanuclear polyoxouranium stone; it

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