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Supramolecular chain polymers formed by N,N'-di(2-ethylhexyl)urea (EHU) dissolved at low concentrations (up to 0.1 mole fraction) in heptane were investigated with the use of the dielectric spectroscopy. The experimental data show an exceptional ability of the chains for the antiparallel self-aggregation due to dipole-dipole interactions, leading to an anomalous dependence of the static permittivity of EHU + heptane solutions on temperature and concentration of the urea. The primary molecular assembly into polymeric chains is therefore