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Plasma constriction is proposed as being inevitable in regions where the local electron density (ne) exceeds some critical value (nec) and electron-electron collisions enhance the rates of H2 dissociation, H-atom excitation, and related associative ionization processes relative to those prevailing in the neighboring nonconstricted plasma region. The 2D modeling identifies a further challenge to high-p operation. The radial uniformities of the CH3 radical and H-atom concentrations above the growing diamond surface both decline with increasi
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