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This paper presents a detailed description of a molecular velocity distribution-based mesoscopic kinetic approach that enables a better understanding of various nonequilibrium hydrodynamic and thermodynamic effects in shock waves, contact discontinuities, and rarefaction waves. This builds on the mesoscopic kinetic approach in a previous investigation into regular reflection shocks by further addressing the mesoscopic physical meaning of kinetic moments from the view of kinetics and the implications of the magnitude and sign of nonequi
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