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024% per cycle. This work provides a synergistic regulation on crystallinity and oxygen deficiency toward rapid and durable sulfur electrochemistry, holding a great promise in developing practically viable Li-S batteries and enlightening material engineering in related energy storage and conversion areas.Silicon-containing block copolymer thin films with high interaction parameter and etch contrast are ideal candidates to generate robust nanotemplates for advanced nanofabrication, but they typically form in-plane oriented microdomains a

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