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Under optimized conditions, the NIE-DSM/HPLC-FLD method gave low limits of detection (0.008-0.034 μg kg-1) and satisfactory extraction recoveries (74.1-101.6%) for five polycyclic aromatic hydrocarbons (PAHs; fluorene, anthracene, pyrene, chrysene and benza)pyrene) in milk samples. The intra-day and inter-day precision, expressed as relative standard deviations, was less then 5.9% and 6.5%, respectively, demonstrating a high precision. Owing to no requirement for electrical power, this method shows great potential for outdoor monitorin