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This work provided a facile method for the preparation of Fe-based carbon materials with high catalytic ability, low metal leaching and easy recycling, showing a broad prospect for environmental applications.For noble metal catalysts such as Au and Ag, the weak adsorption of intermediates is an important factor in limiting the efficiency of CO2 electroreduction. Positively charged metals, which can lower the energy barriers of intermediate reactions, greatly facilitate the rapid conversion of CO2 molecules. In this work, a simple in situ