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These results may help us to understand the diffusion motion of rings in radial poly[n]catenanes from a fundamental point of view and control the sliding dynamics in molecular designs.Pharmaceutical and personal care products (PPCPs) are regarded as an emerging class of contaminants, which are often released directly into the environment, causing severe deleterious effects. In particular, the widely prescribed β-blocker atenolol (At) is alarmingly present in water. Despite the toxicity caused by At, no specific methods are currently ava