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To the end, we selected Quaternary large ammonium aquifer systems in main Yangtze River basins and utilized carbon isotopes in both dissolved natural carbon and inorganic carbon along with characterization of mixed organic matter (DOM) and groundwater biochemistry to reveal components related to the genesis of ammonium. The outcome indicate that high quantities of geogenic ammonium (up to 33.50 mg/L as N) take p
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