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Porous materials have a variety of applications such as catalysis, gas separation, sensing, tissue engineering, sewage treatment, and so on. However, there are still challenges in the synthesis of porous materials with light weight, high porosity, and superhydrophobicity. Herein, we demonstrate one acoustic-controlled microbubble generation method, which is used to synthesize 3D polymer porous materials. The acoustic-controlled microbubble generation based on focused surface acoustic wave (FSAW) is suitable for not only the generation