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This strategy allows the direct alkylation of heteroaromatics in the absence of an external oxidant. A preliminary mechanistic research shows that the present effect probably continues via an intermolecular HAT process.In this work, the preparation of new S-adenosyl-l-methionine (SAM) analogues for sequence specific DNA labeling is assessed. These non-natural analogues, comprising cysteine as opposed to the normal homolog, had been obta