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We further discuss the current limitations of BCP nanopatterning and suggest future research directions to open up new potential application fields.ConspectusFor organic solar cells (OSCs), charge generation at the donor/acceptor interfaces is regarded as a two-step process driven by the interfacial energy offsets, the excitons produced by light absorption are first dissociated into the charge-transfer (CT) states, and then the CT states are further separated into free charge carriers of holes and electrons by overcoming their Coulomb at