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The present study can help people to design the proper crystal plane catalyst to get the target product of PO with high selectivity and activity in the selective oxidation of propylene. Copyright © 2020 American Chemical Society.Growth and physical properties of bulk REBa2Cu3O7-δ (REBCO) superconductors fabricated by the infiltration growth (IG) method strongly depend on the initial size and morphology of the RE2BaCuO5 (211) particles. The present work details the novel method we developed for producing sharp-edged and surface-damaged 21