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The decrease in extractable Cd was strongly related to the increase in poorly crystalline Fe(Ⅱ) mineral phases among the three soils and various soil moisture contents. Although 0.1% nZVI amendment induced the dissolution of Mn oxides, it did not hinder the Cd stabilization in the three soils. Overall, this study indicates that increased amounts of poorly crystalline Fe(Ⅱ) compounds due to nZVI amendment play a critical role in the stabilization of Cd in soils.The global phase-out has decreased the use of polybrominated diphenyl ethers