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All results indicated that the determination of Hg using improved LCGD with the addition of chemical modifiers has high sensitivity, low LOD, well precision and low power consumption. Water samples containing high mercury (10-20 mg L-1) and low mercury (0.2-5 mg L-1) can be determined by improved LCGD-AES with no chemical modifier and 4% methanol, respectively. Adding 4% methanol significantly reduces the matrix effects from real water samples. The measurement results of spiked samples using LCGD-AES are largely consistent with the spike