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Conventional photocatalysts must be activated by ultraviolet or visible light to meet the energy requirement of populating an initial excited state, while infrared light has a high penetration depth to reaction media but does not have enough photon energy to activate conventional photocatalysts. Here, we report the activation of Ag nanoparticles by upconversion nanoparticles (UCNPs) in UCNPs@SiO2@Ag with manipulated energy transfer for infrared photocatalysis. UCNPs can efficiently convert infrared light to visible and ultraviolet ligh

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