https://www.selleckchem.com/pr....oducts/Resveratrol.h
The abundance and geometric features of nonbonding contacts between metal centers and `soft' sulfur atoms bound to a non-metal substituent R were analyzed by processing data from the Cambridge Structural Database. The angular arrangement of M, S and R atoms with ∠(R-S...M) down to 150° was a common feature of the late transition metal complexes exhibiting shortened R-S...M contacts. Several model nickel(II), palladium(II), platinum(II) and gold(I) complexes were chosen for a theoretical analysis of R-S...M interactions using the DFT