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Slow magnetization relaxation characteristic of single-molecule magnet (SMM) behavior was observed for compounds S-1 and S-3. Theoretical calculations were performed to rationalize the magneto-structural relationships.Platinum usually offers the most effective active center for hydrogen evolution reaction (HER), because of the optimal trade-off between the adsorption and desorption of hydrogeN atoms (H*) on Pt atoms. Herein, we report an unusual result regarding the active center of a HER catalyst, which was synthesized by electrodeposi
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