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2% capacity retention, 0.044% fading rate per cycle, and approximately 100% Coulombic efficiency after 200 cycles). This work demonstrates that the few-layered ternary MTMSs are highly applicable for the development of advanced SIB anode materials with high performance.We report a nanocomposite coating for lithium metal protection, which consists of nanosized LiF particles embedded into a PEO polymer matrix. The composite offers a large LiF/PEO interface area throughout the coating, promoting an exceptionally high ionic conductivity of 0.9