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In this report, disulfonic-functionalized acid ionic liquids (DSFAILs) were synthesized effectively, including novel SO3H-functionalized binuclear IL (bis[3-(CH2)3SO3H-1-(CH2)2-Im][HSO4]2). For the biodiesel synthesis, compared with the traditional ILs catalysts, DSFAILs bis[(3-(CH2)3SO3H-1-(CH2)2-Im][HSO4]2, [Im(N (CH2)3SO3H)2][HSO4]) had higher catalytic activity even under mild response problems. Making use of the density useful principle (DFT) strategy, the part of hydrogen bonds in various SO3H-functionalized
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