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The type of the fragrant substituent largely affects the chiral recognition capability of TBDMS-β-CD toward 1-(1-naphthyl)ethylamine in cyclohexane. A TBDMS-β-CD by-product with a p-tolyl substituent has actually an amazing chiral selectivity for the (S)-1-(1-naphthyl)ethylamine over the corresponding (R)-isomer (KS /KR =4.1±0.5), whereas a TBDMS-β-CD derivative with a 2-picolyl substituent programs the inverse chiral selectivity (KR /KS =8.7±0.6). Treatment plan for dise
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