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The aprotic and protic solvents gave a linear plot for the Stokes shifts in a Lippert-Mataga plot, which appeared as two distinct domains in ET(3 scales indicating the presence of hydrogen bondings. It was observed that for compounds 5b - 8b, with (-NMe2) group on the skeleton of phenyl ring, the Lippert-Mataga and Reichardt-Dimroth's plots deviated from linearity signifying that 5b - 8b molecules were involved in specific interaction with protic solvents.Baclofen belongs to skeletal muscle relaxant and is used for the treatment of muscl
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