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A. Duncan, J. Chem. Phys., 2016, 145, 231,101), it appears that the position isomers, because of the binding of the weakly bound Ar messenger, are needed to account for the additional bands in the infrared photodissociation spectrum for Ar3H+. These findings demonstrate the active role of the messenger atom in relaxing some of the selection rules for the bare ion's vibrational transitions - resulting in an augmentation of the bands in the action spectrum.The recently proposed rSCAN functional [ J. Chem. Phys. 2019 150, 161101] is a reg
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