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Capillary electrophoresis is often plagued by unstable and unrepeatable results. In this paper, some novel modes are derived theoretically and illustrated by separation examples, as expected these modes can resist the change of some conditions under certain prerequisites and obtain super stable electropherograms. They are weighted mobility spectrometry, migrated charge spectrometry, charge density spectrometry, molar charge density spectrometry, diffusion coefficient spectrometry, liquid-phase mass spectrometry, and their ratio spectro
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