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SWA is more suitable for retrieving LST in Shanghai during the summer, a season when the temperature and the humidity are both very high in Shanghai. Highest retrieval accuracy could be seen in cultivated land, vegetation, wetland, and water body. SWA was more sensitive to the error caused by land surface emissivity (LSE). In low temperature and a dry winter, RTE, SWA, and SCA are relatively more reliable. Both RTE and SCA were sensitive to the error caused by atmospheric water vapor content. These results can provide a reasonable reference for the