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After modification with 11-mercaptoundecanoic acid and 1-decanethiol, the surfaces also exhibit pH-responsive wettability. The superhydrophobic surfaces with responsive wettability have potential applications in biotechnology and microfluidics.Metal-organic frameworks (MOFs) constructed with mixed ligands have shown great promise in the generation of materials with improved sorption, optical, and electronic properties. With an experimental, spectroscopic, and computational approach, herein, we investigated how the incorporation of diffe