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Blue Phosphorene (BlueP) has been widely researched as a potential material for novel photocatalytic and electronic devices recently. In this letter, due to its similar in-plane hexagonal lattice structure to MoS2, BlueP/MoS2 van der Waals heterostructures were built in six configurations, the II-stacking configuration was the most stable owing to the lowest binding energy obtained from the calculation results. Furthermore, by controlling the external vertical strain, the geometry structures were optimized and the electronic structures of