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These important results are helpful for further designing new metal catalysts for methane activation at the atomic/molecular level.The present work deals with the optical properties of hybrid organic metal halide material namely (C9H8NO)2SnCl6·2H2O. Its structure is built up from isolated [SnCl6]2- octahedral dianions surrounded by Hydroxyl quinolinium organic cations (C9H8NO)+, abbreviated as [HQ]+. Unlike the usual hybrid materials, where metal halide ions are luminescent semiconductors while the organic ones are optically inactive, [HQ]2SnC
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