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Additionally, we probe how the nature of the ligand chemistry affects the radiative lifetime and PL efficiency and find that the ligands do not significantly change the D-A emission dynamics, and all samples retain the long 50-130 μs lifetimes characteristic of these transitions. Finally, we describe three mechanisms that operate to affect the D-A recombination energies (1) X-type ligands that modulate the PBSi-X NC wavefunction; (2) L-type ligands that perturb the donor and acceptor states via a molecular orbital theory picture; and

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