https://www.selleckchem.com/pr....oducts/aprotinin.htm
In transition-metal catalyst structures, both the ligand structure and the initiating group are crucial components for olefin polymerization. Compared to numerous studies on tuning the electronic and steric effects of ligands, there is no report on the comprehensive investigation of initiating groups. In this contribution, five different initiating groups including "NiMe", "NiPh", "Ni(allyl)", "Ni(COD)", and "Ni(acac)/AlEt2Cl" were designed and installed into sterically bulky phosphino-phenolate nickel complexes Ni1-Ni5, respectively,
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