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These results set an ultimate timescale of this exciton development in TMDs and elucidate the extremely quick physical method behind this procedure.Despite the essential significance of efficient and discerning synthesis of widely useful alkylarenes, the direct catalytic C(sp2)-H alkylation of unactivated arenes with a readily readily available alkyl halide remains elusive. Here, we report the catalytic C(sp2)-H alkylation reactions of unactivated arenes with alkyl b

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