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The process of deintercalation passes through vapour tube formation inside the confined space, and this process is initiated by vapour bubble formation. The size of the critical vapour tube required for spontaneous evaporation of WIS from the confinement is also found to depend on the intersurface separation and WIS concentration.The use of a novel inorganic nanoscale cluster (Al[(μ-OH)2CNH3)4]3(NO3)6) was investigated for its utility as a precursor for AlCoOx films. Mixed-metal aluminum and cobalt oxide thin films were solution depos