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Fifty-five samples were collected from topsoils around a petrochemical industrial area at the east of Algiers (Algeria) and analyzed for 16EPA priority PAHs in the aim to determine the concentrations, the distributions, and the possible sources of polycyclic aromatic hydrocarbons (PAHs). The results of the quantification are then devoted to the assessment of the potential risks as the toxicity, the risk for the ecosystem, and the risk for the human health. The sampling sites were classified into four categories rural, suburban, urban,