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From environmental security and resource recovery viewpoint, hydrothermal technology was adopted to recycle Ag, As, and Ga from waste LEDs in present study. Waste LEDs packaging materials (Polyphthalamide (PPA), epoxy resin, and brominated flame retardant (BFR)), which are difficult to degrade under normal conditions, can be effectively decomposed through two steps of hydrothermal treatment. As and Ga were leached and silver was successfully recovered. Under the optimal process parameters (300 ℃, 300r/min, 3% volume ratio of H2O2,400 m