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In the context of the Doce river (Southeast Brazil) Fundão dam disaster in 2015, we monitored the changes in concentrations of metal(loid)s in water and sediment and their particulate and dissolved partitioning over time. Samples were collected before, during, and after the mine tailings arrival to the Doce river estuary (pre-impact 12, 10, 3 and 1 day; acute stage tailing day - TD and 1 day after - DA; chronic stage 3 months and 1 year post-disaster). Our results show that metal(loid) concentrations significantly increased with time af