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This work provides new tips when it comes to development of supported catalysts and offers a theoretical guide for the appropriate verification of SMSI.In this study, carboxymethyl cellulose (CMC) ended up being utilized to support zero-valent iron nanoparticles (CMC-nFe to boost their dispersity and antioxidation for enhanced hexavalent chromium (Cr(VI)) removal. Checking electron microscope (SEM) observation unveiled that the nFe0 agglomerated in clusters, as the C